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61.
我国是煤炭资源大国,煤层气储量规模相当可观,但煤储层又具有低孔、低渗的不足,照搬国外或常规石油天然气的开采程序和方法已被证实是走不通的。应结合实际,根据不同地质条件、不同煤阶的开采程序,进行孔隙特征研究。煤孔隙特征、连通性和吸附能力对煤层气开采影响尤为重要,为研究煤孔隙结构特征随煤变质程度的变化关系及其吸附能力的响应特点,采取不同地区不同变质程度煤样,进行压汞测试和等温吸附实验。实验结果表明,煤孔隙度和平均孔径均随变质程度增加呈现降低—升高—降低的趋势;煤中孔隙连通性随煤变质程度增加逐渐变差;随煤变质程度增加,其最大吸附能力也呈现降低—升高—降低的总体趋势。 相似文献
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Xiangrong Ma Rui Dang Ning Yang Xiao Li Ya zhang Ying Gong Zhipan Liu Wei Guo Yuanyuan Zhang Chunyan Li 《International Journal of Hydrogen Energy》2021,46(44):22842-22851
The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag3VO4 have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag3VO4 (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H2 production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H2 evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H2 evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions. 相似文献
65.
Graded evolution of anisotropic microstructure during sintering from crystal-oriented powder compact
Shoko Baba Alexandre Maître Nicolas Pradeilles Guy Antou Nobuo Saito Satoshi Tanaka 《International Journal of Applied Ceramic Technology》2020,17(2):677-684
Anisotropic sintering, including shrinkage and grain growth, was examined for c-axis-oriented (Sr,Ca)2NaNb5O15 (SCNN) ceramics, which were prepared by colloidal processing under a magnetic field. In the c-axis-oriented SCNN powder compact, shrinkage and grain growth along the c-axis were higher than those along the a-axis. The anisotropic microstructural development was clearly associated with anisotropic sintering shrinkage. X-ray diffraction, scanning electron microscopy, and energy back scattering diffraction showed that the grain growth of oriented particles by including random grains contribute to the development of the oriented microstructure. Finally, the highly crystal-oriented SCNN ceramics with a densified microstructure were obtained through anisotropic sintering. These results clearly showed the potential to develop a well-defined anisotropic microstructure during sintering by designing and controlling the particle packing structure in a powder compact. 相似文献
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刘家山排土场为民采排弃形成,已经出现大规模滑坡。为了保证上下游生产生活设施的安全,依据现场实际情况,结合现场调查,提出了削坡处理的方案。经过治理后,刘家山排土场平稳地渡过了雨季,目前处于稳定状态,达到了治理目的。 相似文献
68.
Xiaoqin Zhang Shugang Ma Ang Shen Jin Zhu Zhisen Shen Jinggang Wang Xiaoqing Liu 《应用聚合物科学杂志》2020,137(44):49365
Poly(butylene terephthalate-co-butylene 2,5-furandicarboxylate) copolyesters (PBTFs) were synthesized from 1,4-butanediol, dimethyl terephthalate (DMT), and 2,5-furandicarboxylic acid (FDCA) by a two-step polymerization method. Their chemical structures were confirmed by Fourier-transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and carbon nuclear magnetic resonance before thermal properties were explored with differential scanning calorimeter and thermogravimetric analyzer. Results showed that PBTFs changed from semi-crystalline to completely amorphous when the content of FDCA unit was increased to 45 mol% at first, and then became crystallographic again with the further increment of FDCA unit to 75 mol%. For their mechanical properties, the tensile modulus and strength showed the similar trend, decreasing firstly and then increasing later. Their barrier to carbon dioxide and oxygen became better with the increasing of furan content due to the rigidity and higher polarity of furan ring. The performance of PBTFs copolyesters was investigated clearly, and the relative content of FDCA and DMT can be adjusted to satisfy different performance requirements. 相似文献
69.
随钻扩眼工具及技术研究 总被引:1,自引:0,他引:1
基于随钻扩眼技术优势的分析,研究了机械式、液压式和偏心式随钻扩眼工具执行机构和扩眼总成的机构原理,并介绍了国内所开展的相关研究。文章提出应加强现有工具的适应性和匹配性研究,发掘各类工具的优势。优化执行机构、扩眼总成和水力机构、重视底部钻具组合力学特性的分析是今后发展和完善随钻扩眼工具及技术的几个重要内容。实践表明,随钻扩眼技术在处理井下复杂情况、降低钻井综合成本、提高钻井速度、提高建井质量和安全性等方面具有显著的优势,随钻扩眼工具也正逐渐成为一种重要的石油钻井配套工具。 相似文献
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